(+)-(18-Crown-6)-2,3,11,12-tetracarboxamide

Product Name (+)-(18-Crown-6)-2,3,11,12-tetracarboxamide
CAT No. CS-T-51311
CAS No. 57207-22-4
Category Impurities
Stock Enquire
Mol. Wt. Not Available
Mol. For. Not Available
Hazardous This is not a Hazardous Compound
COA View Sample COA
MSDS View Sample MSDS
Canonical Smiles CC1C(OCCOCCOC(C(OCCOCCO1)C(=O)N(C)C)C(=O)N(C)C)C(=O)N(C)C
InchIKey JRYSSONMMLCWOV-WJFTUGDTSA-N
Inchl InChI=1S/C22H41N3O9/c1-16-17(20(26)23(2)3)32-13-9-30-11-15-34-19(22(28)25(6)7)18(21(27)24(4)5)33-14-10-29-8-12-31-16/h16-19H,8-15H2,1-7H3/t16-,17+,18+,19+/m0/s1
IUPAC (2R,3R,11R,12S)-2-N,2-N,3-N,3-N,11-N,11-N,12-heptamethyl-1,4,7,10,13,16-hexaoxacyclooctadecane-2,3,11-tricarboxamide
Controlled No
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(+)-(18-Crown-6)-2,3,11,12-tetracarboxamide, also known as (R,R)-TMC or (R,R)-2,3,11,12-tetracarboxamide-18-crown-6, is a chiral, macrocyclic compound that is widely used in chemistry as a chiral selector in enantioselective chromatography and as a chiral auxiliary in asymmetric synthesis. It is a derivative of 18-crown-6, a cyclic ether with six oxygen atoms that can complex with metal cations to form stable complexes. The tetracarboxamide derivative of 18-crown-6 has four carboxamide substituents at the 2, 3, 11, and 12 positions of the crown ring, which enhance its solubility in organic solvents and increase its selectivity for certain metal ions. (+)-(18-Crown-6)-2,3,

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