Zineb

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Catalog Number : CS-T-87452
CAS Number : 12122-67-7
Status : Available for immediate dispatch
Category : Pesticide Standards
Molecular Weight : 275.74 mol/g
Molecular Formula : C₄H₆N₂S₄Zn
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Status : Available for immediate dispatch
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Hazardous Compound : Yes

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Canonical SMILES : C(CNC(=S)[S-])NC(=S)[S-].[Zn+2]
Isomeric SMILES : C(CNC(=S)[S-])NC(=S)[S-].[Zn+2]
InChI : InChI=1S/C4H8N2S4.Zn/c7-3(8)5-1-2-6-4(9)10;/h1-2H2,(H2,5,7,8)(H2,6,9,10);/q;+2/p-2
InchIKey : AMHNZOICSMBGDH-UHFFFAOYSA-L
IUPAC Name : zinc;N-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate
Exact Mass : 273.870525
Color : Powder or crystals from chloroform + alcohol
Odor : Practically odorless
Melting Point : 157 °C (decomposes)
Boiling Point : decomposes
Solubility : less than 1 mg/mL at 77° F (NTP, 1992)
Density : Approx 1.74 at 20 °C
Chemical Classes : Pesticides -> Dithiocarbamates (Pesticide)
Use Classification : Agrochemicals -> Fungicides
Hazard Class : STOT SE 3
Description : Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).
Disposal Methods : Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number U114, must conform with USEPA regulations in storage, transportation, treatment and disposal of waste.
EC Number : 235-180-1
Vapor Pressure : 0.00000008 [mmHg]
Antidoteand Emergency Treatment : Immediate first aid: Remove patient from contact with the material. Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. /Dithiocarbamates and Related Compounds/
Human Toxicity Excerpts : /HUMAN EXPOSURE STUDIES/ The irritant and allergic potential of most dithiocarbamates is evident in occupational exposure. Skin irritation and sensitization were studied in man using a conventional patch test. A cotton square was dipped in 19% nabam solution and placed on the inner surface of the forearm, and, 14 days later, this procedure was repeated on the opposite forearm. Zineb was tested in the same manner, except that the cotton square was dipped in 65% wettable powder. The patches were left in place for 48 hr. Of the 25 subjects included in the nabam study, 2 showed irritation (mild erythema and itching). Thirteen of the 25 reacted to the retest (from mild erythema to severe erythema, edema, and vesiculation), indicating sensitization. Of the 50 subjects used in the zineb study, no reaction at all was seen in 49 of them. One reacted in such a way that it indicated primary irritation rather than sensitization ...

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